Guest Seminar -  Phase Engineering of Nanomaterials (PEN)

In this talk, I will summarize the recent research on phase engineering of nanomaterials (PEN) in my group, particularly focusing on the rational design and synthesis of novel nanomaterials with unconventional phases for various promising applications. For example, by using wet-chemical methods, for the first time, we have successfully prepared novel Au nanostructures (e.g., the hexagonal-close packed (hcp) 2H-Au nanosheets, 4H-Au nanoribbons, and crystal-phase heterostructured 4H/fcc and fcc/2H/fcc heterophase Au nanorods), epitaxially grown metal nanostructures on the aforementioned unconventional Au nanostructures and 2H-Pd nanoparticles, and amorphous/crystalline heterophase Pd, PdCu, Rh and Rh alloy nanosheets. In addition, by using gas-solid reactions, metastable 1T'-phase group VI transition metal dichalcogenides (TMDs), e.g., WS2, WSe2, MoS2, MoSe2, WS2xSe2(1-x) and MoS2xSe2(1-x), have been prepared. Moreover, the phase transformation of TMDs during our developed electrochemical Li-intercalation process has also be observed. Impressively, the lithiation-induced amorphization of Pd3P2S8 has been achieved. Currently, my group focuses on the investigation of phase-dependent physicochemical properties and applications in catalysis, (opto-)electronic devices, clean energy, chemical and biosensing, surface enhanced Raman scattering, waveguide, photothermal therapy, etc., which we believe is quite unique and very important not only in fundamental studies, but also in future practical applications. Importantly, the concepts of phase engineering of nanomaterials (PEN), crystal-phase heterostructures, and heterophase nanomaterials are proposed.